• H. Kohlmann, Solid-gas reactions in synthetic chemistry - what can we learn from reaction pathways?, Russ. Chem. Rev. 2020, 89, 275-280
  • H. Kohlmann, A. Rauchmaul, S. Keilholz, A. Franz, Crystal structure and thermal behavior of SbC2O4OH and SbC2O4OD, Inorganics 2020, 8, 21, doi: 10.3390/inorganics8030021
  • F. Gehlhaar, S. Keilholz, H. Kohlmann, In situ X-ray powder diffraction study of the reactions of CrO2 and TlPd3O4 with hydrogen, Z. Anorg. Allg. Chem. 2020, 646, in print, doi: 10.1002/zaac.201900323
  • C. Pflug, H. Kohlmann, Structural Distortion in Perovskite Type KCaH3-xFx (0.54 ≤ x ≤ 3), Z. Anorg. Allg. Chem. 2020, 646, 175-179, doi: 10.1002/zaac.201900309
  • H. Kohlmann, Rare earth metal based hydride materials, in: R. Pöttgen, T. Jüstel, C. A. Strassert (Eds.), Rare Earth Chemistry, de Gruyter, Berlin, 2020


  • A. Werwein, T. C. Hansen, H. Kohlmann, Size Matters: New Zintl Phase Hydrides of REGa (RE = Y, La, Tm) and RESi (RE = Y, Er, Tm) with Large and Small Cations, Crystals 2019, 9, 600; doi: 10.3390/cryst9110600
  • N. Zapp, H. Auer, H. Kohlmann, YHO, an Air-Stable Ionic Hydride, Inorg. Chem. 2019, 58, 14635−14641, doi: 10.1021/acs.inorgchem.9b02308
  • H. Kohlmann, Looking into the Black Box of Solid-State Synthesis, Eur. J. Inorg. Chem. 2010, 4174-4180, doi: 10.1002/ejic.201900733
  • H. Auer, F. Yang, H. Y. Playford, T. C. Hansen, A. Franz, H. Kohlmann, Covalent Si-H bonds in the Zintl phase hydride CaSiH1+x (x ≤ 1/3), Inorganics 2019, 7, 106, doi: 10.3390/inorganics7090106
  • L. Chen, P. Cheng, Z. Zhang, L. He, Y. Jiang, G. Li, X. Jing, Y. Qin, M. Yin, T.-S. Chan, B. Hong, S. Tao, W. Chu, Z. Zhao, H. Ni, H. Kohlmann, O. Oeckler, Reduced local symmetry in lithium compound Li2SrSiO4 distinguished by a Eu3+ spectroscopy probe, Adv. Sci. (Weinheim, Ger.) 2019, 6, 180212, doi: 10.1002/advs.201802126
  • R. Guehne, H. Auer, H. Kohlmann, J. Haase, M. Bertmer, Determination of element-deuterium bond lengths in Zintl phase deuterides by 2H-NMR, Phys. Chem. Chem. Phys. 2019, 21, 10594-10602 , doi
  • A. Werwein, C. Benndorf, M. Bertmer, A. Franz, O. Oeckler, H. Kohlmann, Hydrogenation Properties of LnAl2 (Ln = La, Eu, Yb), LaGa2, LaSi2 and the Crystal Structure of LaGa2H0.71(2), Crystals 2019, 9, 193, doi: 10.3390/cryst9040193
  • H. Kohlmann, The crystal structure of cubic C-type samarium sesquioxide, Sm2O3, Z. Naturforsch., B: Chem. Sci. 2019, 74, 433-435, doi:
  • H. Auer, R. Nedumkandathil, U. Häussermann, H. Kohlmann, The Hydrogenation of the Zintl Phase NdGa studied by in situ Neutron Diffraction, Z. Anorg. Allg. Chem. 2019, 645, 175-181, doi: 10.1002/zaac.201800459


  • A. Götze, H. Auer, R. Finger, T. C. Hansen, H. Kohlmann, A sapphire single-crystal cell for in situ neutron powder diffraction of solid-gas reactions, Phys. B (Amsterdam, Neth.) 2018, 551, 395-400. DOI:10.1016/j.physb.2017.11.024
  • I. G. Aviziotis, A. Götze, F. Göhler, H. Kohlmann, M. Armbrüster, ,
    Activation of the Highly-Selective Pd11Bi2Se2 during the Semi-Hydrogenation of Acetylene,
    Z. Anorg. Allg. Chem. 2018, 644, 1777-178. DOI:10.1002/zaac.201800342
  • N. Zapp, H. Kohlmann,
    The lanthanide hydride oxides SmHO and HoHO,
    Z. Naturforsch., B: Chem. Sci. 2018, 73, 535-538. DOI:10.1515/znb-2018-0112
  • F. Gehlhaar, R. Finger, N. Zapp, M. Bertmer, H. Kohlmann,
    LiSr2SiO4H, an Air-Stable Hydride as Host for Eu(II) Luminescence,
    Inorg. Chem. 2018, 57, 11851−11854, DOI:10.1021/acs.inorgchem.8b01780
  • A. Götze, J. Möllmer, H. Kohlmann,
    From the Laves phase CaRh2 to the Perovskite CaRhH3 - in Situ Investigation of Hydrogenation Intermediates CaRh2Hx ,
    Inorg. Chem 2018, 57, 10925-10934, DOI:10.1021/acs.inorgchem.8b01547
  • E. Yu. Zakharova, N. A. Andreeva, S. M. Kazakov, A. Götze, H. Kohlmann, A. N. Kuznetsov,
    Ternary palladium-indium-phosphorus and platinum-indium-phosphorus compounds based on the Cu3Au-type: Structure, bonding, and properties,
    J. Solid State Chem. 2018, 265, 266-273, DOI:10.1016/j.jssc.2018.06.012
  • A. Werwein, H. Auer, L. Kuske, H. Kohlmann,
    From Metallic LnTt (Ln = La, Nd; Tt = Si, Ge, Sn) to Electron-precise Zintl Phase Hydrides LnTtH,
    Z. Anorg. Allg. Chem. 2018, 644, 1532-1539, DOI:10.1002/zaac.201800062
  • G. Lefevre, A. Herfurth, H. Kohlmann, A. Sayede, T. Wylezich, S. Welinski, P. Duarte Vaz, S. F. Parker, J. F. Blach, P. Goldner, N. Kunkel,
    Electron–Phonon Coupling in Luminescent Europium-Doped Hydride Perovskites Studied by Luminescence Spectroscopy, Inelastic Neutron Scattering, and First-Principles Calculations,
    J. Phys. Chem. C 2018, 122,, 10501–10509, DOI:10.1021/acs.jpcc.8b01011
  • A. Götze, N. Zapp, A. J. Peretzki, V. Pomjakushin, T. C. Hansen, H. Kohlmann,
    In Situ Hydrogenation and Crystal Chemistry Studies of Co2Si type compounds MgPd2 and Pd2Zn ,
    Z. Anorg. Allg. Chem. 2018, 644, 367-375, DOI:10.1002/zaac.201700434
  • H. Kohlmann, T. C. Hansen, V. Nassif,
    The magnetic structure of SmCo5 from 5 K to the Curie temperature,
    Inorg. Chem. 2018, 57, 1702-1704.
  • H. Auer, S. Weber, T. C. Hansen, D. M. Többens, H. Kohlmann,
    Reversible hydrogenation of the Zintl phases BaGe and BaSn studied by in situ diffraction,
    Z. Kristallogr. 2018, 233, 399-409, DOI:10.1515/zkri-2017-2142
  • A. Götze, S. Schmorl, A. Kuznetsov, H. Kohlmann,
    Vacancy Ordering in Pd11Bi2Se2 - Crystal Structure and Properties,
    J. Alloys Compd. 2018, 735, 1914-1920.
  • A. Götze, T. C. Hansen, H. Kohlmann,
    The reversible hydrogenation of BiPd3 followed by in situ methods and the crystal structure of PbPd3D0.13(1),
    J. Alloys Compd. 2018, 731, 1001-1008.
  • C. Pflug, A. Franz, H. Kohlmann,
    Crystal structure and europium luminescence of NaMgH3-xFx,
    J. Solid State Chem. 2018, 258, 391-396.
  • A. Götze, H. Auer, R. Finger, T. C. Hansen, H. Kohlmann,
    A sapphire single-crystal cell for in situ neutron powder diffraction of solid‐gas reactions,
    Phys. B 2018, 551, 395-400, DOI:10.1016/j.physb.2017.11.024


  • H. Kohlmann, 100 years in situ diffraction, Z. Kristallogr. 2017, 232, 843-849. DOI:10.1515/zkri-2017-2114
  • A. Werwein, F. Maaß, L. Y. Dorsch, O. Janka, R. Pöttgen, T. C. Hansen, J. Kimpton, H. Kohlmann,
    Hydrogenation properties of Laves phases LnMg2 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er, Tm, Yb), Inorg. Chem. 2017, 56, 15006-15014 . DOI:10.1021/acs.inorgchem.7b02319
  • M. Veith, A. Walgenbach, V. Huch, H. Kohlmann, Aluminium/Nitrogen Cycles and an Open Cage with Al-H and N-H Functions, Z. Anorg. Allg. Chem. 2017, 643, 1233–1239.
  • M. Voss, H. Kohlmann, Ion segregation and electrostatic imbalance in metal hydrides, Z. Anorg. Allg. Chem. 2017, 643, 1038-1044.
  • H. Auer, H. Kohlmann, In situ Investigations on the Formation and Decomposition of KSiH3 and CsSiH3, Z. Anorg. Allg. Chem. 2017, 643, 945-951. DOI:10.1002/zaac.201700164
  • H. Auer, R. Schlegel, O. Oeckler, H. Kohlmann, Structural and Electronic Flexibility in Hydrides of Zintl Phases with Tetrel-Hydrogen and Tetrel-Tetrel Bonds, Angew. Chem. Int. Ed. 2017, 56. DOI:10.1002/anie.201706523 (english version)
    DOI:10.1002/ange.201706523 (deutsche Version)
  • H. Auer, D. Wallacher, T. C. Hansen, H. Kohlmann, In Situ Hydrogenation of the Zintl Phase SrGe, Inorg. Chem. 2017, 56, 1072-1079. DOI:10.1021/acs.inorgchem.6b01945
  • H. Auer, R. Guehne, M. Bertmer, S. Weber, P. Wenderoth, T. C. Hansen, J. Haase, H. Kohlmann, Hydrides of Alkaline Earth-Tetrel (AeTt) Zintl Phases: Covalent Tt-H Bonds from Silicon to Tin, Inorg. Chem. 2017, 56, 1061-1071. DOI:10.1021/acs.inorgchem.6b01944
  • A. Götze, H. Kohlmann, Palladium Hydride and Hydrides of Palladium Rich Compounds, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier 2017, DOI:10.1016/B978-0-12-409547-2.12204-8


  • H. Kohlmann, C. Hein, R. Kautenburger, T. C. Hansen, C. Ritter, S. Doyle, Crystal structure of monoclinic samarium and cubic europium sesquioxides and bound coherent neutron scattering lengths of the isotopes Sm-154 and Eu-153, Z. Kristallogr. 2016, 231, 517-523.
  • H. Kohlmann, Von der Natur des Wasserstoffs in Metallen, Nachr. Chem. 2016, 64, 1185-1187 .
  • G. Behrendt, C. Reichert, H. Kohlmann, Hydrogenation Reaction Pathways in the Systems Li3N-H2, Li3N-Mg-H2, and Li3N-MgH2-H2 by in Situ X-ray Diffraction, in Situ Neutron Diffraction, and in Situ Thermal Analysis, J. Phys. Chem. C 2016, 120, 13450-13455.
  • W. Li, V. R. Celinski, J. Weber, N. Kunkel, H. Kohlmann, J. Schmedt auf der Günne, Homogeneity Q1 Q2 of doping with paramagnetic ions by NMR, Phys. Chem. Chem. Phys. 2016, 18, 9752-9757.
  • A. Götze, J. M. Sander, H. Kohlmann, Crystal Structures and Hydrogenation Properties of Palladium Rich Compounds with Elements from Groups 12-16, Z. Naturforsch., B: Chem. Sci. 2016, 71, 503-508.
  • N. Kunkel, R. Böttcher, T. Pilling, H. Kohlmann, A. Pöppl, Eu2+-Containing Luminescent Perovskite-Type Hydrides Studied by Electron Paramagnetic Resonance, Z. Phys. Chem. 2016, 230, 931-942.
  • N. Kunkel, H. Kohlmann, Ionic mixed hydride fluoride compounds: stabilities predicted by DFT, synthesis and luminescence of divalent europium, J. Phys. Chem. C 2016, 120, 10506-10511.
  • H. Kohlmann, M. Vasseur, A. Sayede, G. Lefevre, J.M. Sander, S. Doyle, Crystal structure and hydrogenation properties of Pd5As, J. Alloys Compd. 2016, 664, 256-265.


  • N. Kunkel, D. Rudolph, A. Meijerink, S. Rommel, R. Weihrich, H. Kohlmann, T. Schleid, Green Luminescence of Divalent Europium in the Hydride Chloride EuHCl, Z. Anorg. Allg. Chem. 2015, 641, 1220-1224.
  • A. Walgenbach, M. Veith, V. Huch, H. Kohlmann, New molecular aluminium chloride amides [HClAlNEt2]2 and [Cl2AlNEt2]2 and their boranate analogues [H(BH4)AlNEt2]2 and [(BH4)2AlNEt2]2, Z. Anorg. Allg. Chem. 2015, 641, 394-399.
  • R. Hahn, N. Kunkel, C. Hein, R. Kautenburger, H. Kohlmann, Recovery rate and homogeneity of doping europium into luminescent metal hydrides by chemical analysis, RSC Adv. 2015, 5, 9722-9728.
  • M. Jehle, A. Hoffmann, H. Kohlmann, Harald Scherer, Caroline Röhr, The 'sub' metallide oxide hydrides Sr21Si2O5H12+x and Ba21M2O5H12+x (M = Zn, Cd, Hg, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi), J. Alloys Compd. 2015, 623, 164-177.
  • N. Kunkel, C. Reichert, M. Springborg, D. Wallacher, H. Kohlmann, Hydrogenation properties of LixSr1-xAlSi studied by quantum-chemical methods (0 ≤ x ≤ 1) and in-situ neutron powder diffraction (x = 1), J. Solid State Chem. 2015, 221, 318-324.


  • T. Hansen, H. Kohlmann , Chemical Reactions followed by in situ Neutron Powder Diffraction, Z. Anorg. Allg. Chem. 2014, 640, 3044-3063.
  • M. Köpf, N. Eckstein, D. Pfister, C. Grotz, I. Krüger, M. Greiwe, T. Hansen, H. Kohlmann, T. Nilges, Access and in situ Growth of Phosphorene-Precursor Black Phosphorus, J. Crystal Growth 2014, accepted.
  • K. L. A. Belener, H. Kohlmann, Reaction pathways of oxide-reduction-diffusion (ORD) synthesis of SmCo5 and in situ study of its hydrogen induced amorphization (HIA), J. Magn. Magn. Mater. 2014, 370, 134-139.
  • H. Auer, H.Kohlmann, Reinvestigation of Crystal Structure and Non-Stoichiometry in Copper Hydride, CuH1-x (0 ≤ x ≤ 0.26), Z. Anorg. Allg. Chem. 2014, 640, 3159-3165.
  • N. Kunkel, A. Meijerink, H. Kohlmann, Variation of the Eu(II) emission wavelength by substitution of fluoride by hydride in fluorite-type compounds EuHxF2-x (0.20 ≤ x ≤ 0.67), Inorg. Chem. 2014, 53, 4800-4802.
  • N. Kunkel, A. Meijerink, M. Springborg, H. Kohlmann,Eu(II) luminescence in the perovskite host lattices KMgH3, NaMgH3 and mixed crystals LiBaxSr1-xH3, J. Mater. Chem. C 2014, 2, 4799-4804.
  • A. Götze, P. Urban, O. Oeckler, H. Kohlmann, Synthesis and crystal structure of Pd5InSe, Z. Naturforsch., B: Chem. Sci. 2014, 69, 417-422.
  • J. N. Becker, J. Bauer, A. Giehr, P. I. Chu, N. Kunkel, M. Springborg, H. Kohlmann, Electronic structure of ternary rhodium hydrides with lithium and magnesium, Inorg. Chem. 2014, 53, 1135-1143.
  • N. Kunkel, A. Meijerink, H. Kohlmann, Bright yellow and green Eu(II) luminescence in LiSrH3, LiBaH3 and their corresponding deuterides, Phys. Chem. Chem. Phys. 2014, 16, 4807-4813.


  • H. Kohlmann, N. Kurtzemann, T. C. Hansen, Metal hydride formation in palladium and palladium rich intermetallic compounds studied by in situ neutron diffraction,Powder Diffr. 2013, 28 (S2), 242-255.
  • P. Wenderoth, H. Kohlmann, In Situ Neutron Powder Diffraction of the Formation of SrGa2D2, and Hydrogenation Behavior of YbGa2 and EuGa2, Inorg. Chem. 2013, 52, 10525-10531.
  • J.-C. Rybak, M. Hailmann, P. R. Matthes, A. Zurawski, J. Nitsch, A. Steffen, J. G. Heck, C. Feldmann, S. Götzendörfer, J. Meinhardt, G. Sextl, H. Kohlmann, S. J. Sedlmaier, W. Schnick, K. Müller-Buschbaum, Metal-Organic Framework Luminescence in the Yellow Gap by Codoping of the Homoleptic Imidazolate 3 [Ba(Im)2] with Divalent Europium, J. Am Chem. Soc. 2013, 135, 6896-6902.
  • M. Widenmeyer, R. Niewa, T. C. Hansen, H. Kohlmann, In situ Neutron Diffraction as a Probe on Formation and Decomposition of Nitrides and Hydrides: A Case Study, Z. Anorg. Allg. Chem. 2013, 639, 285-295.
last modified: 08.04.2020